For the first part, check the level of all the fluids under the hood. That should tell you what's on the ground.
Usually a head gasket leak is internal. You wouldn't see it on the ground. A way to tell if you do have a head gasket leak is to check the oil and see if it looks like chocolate milk. This means that coolant is getting into your oil. You can check the coolant for the same thing.
For your second question if the smoke didn't last too long, didn't look too white, or didn't smell sweet, then most likely it was condensation which is normal.